Isotopes of berkelium

Berkelium (97Bk) is an artificial element, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. The first isotope to be synthesized was 243Bk in 1949. There are nineteen known radioisotopes, from 233Bk to 253Bk (except 235Bk and 237Bk), and seven nuclear isomers. The longest-lived isotope known is 247Bk with a half-life of 1,380 years; however 248Bk, which has not been observed to decay, may live longer.

Isotopes of berkelium (97Bk)
Main isotopes Decay
Isotope abun­dance half-life (t1/2) mode pro­duct
245Bk synth 4.94 d ε 245Cm
α 241Am
246Bk synth 1.80 d β+ 246Cm
α 242Am
247Bk synth 1380 y α 243Am
248Bk synth >9 y α 244Am
249Bk synth 327.2 d β 249Cf
α 245Am
SF

The isotope commonly used in study, though, is 249Bk as is it the only that can be usefully extracted from reactor actinides and the only ever available in weighable quantity.

List of isotopes


Nuclide
Z N Isotopic mass (Da)
Half-life
Decay
mode

Daughter
isotope

Spin and
parity
Excitation energy
233Bk 97 136 233.05665(25)# 40(30) s α (82%) 229Am 3/2−#
β+? (18%) 233Cm
234Bk 97 137 234.05732(16)# 20(5) s α (>80%) 230Am 3−#
β+ (<20%) 234Cm
236Bk 97 139 236.05748(39)# 26(10) s β+ (99.96%) 236Cm 4+#
β+, SF (0.04%) (various)
238Bk 97 141 238.05820(28)# 2.40(8) min β+ (99.95%) 238Cm 1#
β+, SF (0.048%) (various)
239Bk 97 142 239.05824(22)# 100# s β+ 239Cm (7/2+)
240Bk 97 143 240.05976(16)# 4.8(8) min β+? 240Cm 7−#
α? 236Am
β+, SF (0.0013%) (various)
241Bk 97 144 241.06010(18)# 4.6(4) min β+ 241Cm (7/2+)
242Bk 97 145 242.06200(14)# 7.0(13) min β+ 242Cm 3+#
β+, SF (<3×10−5%) (various)
242mBk 2000(200)# keV 600(100) ns SF (various)
243Bk 97 146 243.063006(5) 4.6(2) h β+ (99.85%) 243Cm 3/2−
α (0.15%) 239Am
244Bk 97 147 244.065179(15) 5.02(3) h β+ (99.994%) 244Cm 4−
α (0.006%) 240Am
244mBk 1500(500)# keV 820(60) ns SF (various)
245Bk 97 148 245.0663598(19) 4.95(3) d EC (99.88%) 245Cm 3/2−
α (0.12%) 241Am
246Bk 97 149 246.06867(6) 1.80(2) d β+ 246Cm 2(−)
247Bk 97 150 247.070306(6) 1.38(25)×103 y α 243Am 3/2−
SF? (various)
248Bk 97 151 248.07314(5) >9 y α? 244Am 6+#
EC? 248Cm
β? 248Cf
248mBk −20(50) keV 23.7(2) h β (70%) 248Cf 1(−)
EC (30%) 248Cm
249Bk 97 152 249.0749831(13) 327.2(3) d β 249Cf 7/2+
α (0.00145%) 245Am
SF (4.7×10−8%) (various)
249mBk 8.777(14) keV 300 μs IT 249Bk 3/2−
250Bk 97 153 250.078317(3) 3.212(5) h β 250Cf 2−
250m1Bk 35.59(10) keV 29(1) μs IT 250Bk 4+
250m2Bk 85.6(16) keV 213(8) μs IT 250Bk 7+
251Bk 97 154 251.080761(12) 55.6(11) min β 251Cf (3/2−)
251mBk 35.5(13) keV 58(4) μs IT 251Bk (7/2+)
252Bk 97 155 252.08431(22)# 1.8(5) min β 252Cf
253Bk 97 156 253.08688(39)# 60# min β? 253Cf 3/2-#
This table header & footer:
  1. mBk – Excited nuclear isomer.
  2. ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. Modes of decay:
  5. ( ) spin value – Indicates spin with weak assignment arguments.
  6. # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  7. NUBASE2020 question-marks this decay, but it has been observed directly, see e.g. the IAEA Chart of Nuclides.
  8. Order of ground state and isomer is uncertain.
  9. Most common isotope

Actinides vs fission products

Actinides by decay chain Half-life
range (a)
Fission products of 235U by yield
4n
(Thorium)
4n + 1
(Neptunium)
4n + 2
(Radium)
4n + 3
(Actinium)
4.5–7% 0.04–1.25% <0.001%
228Ra 4–6 a 155Euþ
248Bk > 9 a
244Cmƒ 241Puƒ 250Cf 227Ac 10–29 a 90Sr 85Kr 113mCdþ
232Uƒ 238Puƒ 243Cmƒ 29–97 a 137Cs 151Smþ 121mSn
249Cfƒ 242mAmƒ 141–351 a

No fission products have a half-life
in the range of 100 a–210 ka ...

241Amƒ 251Cfƒ 430–900 a
226Ra 247Bk 1.3–1.6 ka
240Pu 229Th 246Cmƒ 243Amƒ 4.7–7.4 ka
245Cmƒ 250Cm 8.3–8.5 ka
239Puƒ 24.1 ka
230Th 231Pa 32–76 ka
236Npƒ 233Uƒ 234U 150–250 ka 99Tc 126Sn
248Cm 242Pu 327–375 ka 79Se
1.33 Ma 135Cs
237Npƒ 1.61–6.5 Ma 93Zr 107Pd
236U 247Cmƒ 15–24 Ma 129I
244Pu 80 Ma

... nor beyond 15.7 Ma

232Th 238U 235Uƒ№ 0.7–14.1 Ga
  • ₡,  has thermal neutron capture cross section in the range of 8–50 barns
  • ƒ,  fissile
  • №,  primarily a naturally occurring radioactive material (NORM)
  • þ,  neutron poison (thermal neutron capture cross section greater than 3k barns)

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